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OZONOLYSIS |
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Ozonolysis
is a highly effective oxidation stage in organic
process technology. A number of reactions of organic
compounds with ozone and the production of ozonides
are reviewed, e.g. ozonide formation, reaction
of ozone to form aldehydes, di-aldehydes, carboxylic
acids, etc. These reactions concern the use of
ozone under special conditions i.e. fast kinetic
reactions, highly inflammable and potentially
explosive materials with a toxic gas. Based on
practical experience in designing and operating
ozonolysis systems, not just from the scientific
view, the main operating parameters that must
be considered when applying the process are discussed.
These are shown to be the choice of solvent, the
temperature of the process, the design of the
reactor, the handling of aerosols,effects the
residual ozone and the handling of off gases.
Provided the correct chemical engineering approach
is applied ozonolysis is an economic alternative
in numerous chemical process. |
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Ozone
is the only oxidant that can be used in a homogenous
system that does not involve the addition of water
. All the oxidant form, in addition to producing
the desired product, by products which have to
be separated from the product either immediately
prior or subsequent to the following treatment
stages. For example, hydrogen peroxide can only
be used with water which may not be beneficial
to the overall process if at some later stage
it has to be removed . Ozonolysis is the name
given to the reaction of ozone with organic compounds,
dissolved in a solvent and whereby ozonides are
formed. |
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Ozonolysis
is the addition of the whole ozone molecule(O3)
into the compound , i.e. all 3 oxygen atoms, it
is not a substitution of an element or a molecule
in the compound as is the case in the oxidant
reactions. As such the process is exothermic and
therefore implying that to maintain stable conditions
an efficient cooling of the process is a prerequisite.
The ozonides so formed are also on stable at low
temperature and requiring that the reactor and
subsequent process equipment be kept at temperature
lower than the ozonide disintegration level. |
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Ozonolysis
has been acknowledge as a highly effective oxidation
stage in organic process technology for long time
. However, the implementation of the ozonolysis
process stage in a full-scale plant presents significant
engineering problems that have to be solved. It
is largely for this reason that the process has
not been as widely applied as would expect ed when
considering all the benefits that come with the
use of ozone. Based on practical experience in designing
and operating ozonolysis system this paper describes
the main criteria that must be considered when applying
the process in order to be successful. It also covers
the handling and the safety aspects of using ozone,
itself a toxic gas and always present in a greater
volume of oxygen, under often special conditions
i.e. materials having fast kinetic reactions, highly
inflammable and potentially explosive. Provided
the correct chemical engineering approach is applied
ozonolysis can no longer be considered, an exotic
process. It can be made safe and can be applied
as an economic alternative oxidant in numerous chemical
processes. |
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| Characteristics |
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Reactor |
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Residual Ozone |
| Toxicity
Physical Characteristics
Solubility in Water and Solvents |
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Reactor Design
Mass Transfer
Ratio of Diameter:height
External Reaction |
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Necessity
Thermal Process
Chemical Process
Control |
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